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Citric Acid

INCI

Citric Acid

Safe

Natural acid used to lower pH. Also acts as a chelating agent and antioxidant synergist.

Last reviewed October 7, 2026 · Always verify against the current Health Canada Cosmetic Ingredient Hotlist before use.

CAS Number

77-92-9

Typical Usage Rate

0.1% - 3%

Formulator's quick answer

How Citric Acid works in a cosmetic formula

Citric acid is a water-soluble acid used mainly to lower and fine-tune the final pH of water-based cosmetics. Formulators normally add it as a pre-diluted solution in small increments, measure again after thorough mixing, and confirm the finished product remains inside the preservative system's effective pH range.

Practical guidance

Formulation notes

01

Treat it as a pH control tool

Citric acid can support product stability and preservation by helping a formula reach its target pH, but it is not a complete preservative system. Establish the target from the formula, preservative supplier documentation, packaging, and intended use rather than choosing a pH from the ingredient alone.

02

Add through the water phase

Prepare a known aqueous dilution so small corrections are easier to reproduce. Add gradually, mix completely, and record both the dilution strength and amount added. Recheck the batch after it has cooled because temperature and incomplete equilibration can change the apparent reading.

03

Validate the finished formula

Use a calibrated pH meter suitable for the product rather than relying only on paper strips. A successful bench adjustment still needs stability testing, packaging compatibility work, and appropriate microbiological testing before sale.

Where formulators use it

  • Lotions, creams, and other emulsions that need final pH adjustment
  • Shampoos, body washes, and liquid cleansers
  • Water-based gels, mists, and toners
  • Documented batch corrections during scale-up

Verify before production

  • Supplier specification and whether the material is anhydrous or hydrated
  • The preservative system's documented working pH range
  • The finished product's pH after cooling and during stability testing
  • Current Hotlist status and the exact concentration reported on the CNF

Evidence trail

Sources and review notes

Editorial review: October 7, 2026

Sources support ingredient identity, regulatory checks, and formulation context. Supplier specifications and finished-product testing remain necessary for each formula and batch.

Canadian suppliers

Pricing is for reference. Always confirm current price, lead time, and Certificate of Analysis directly with the supplier.

SupplierLocationPrice/kgMin Order
New Directions AromaticsMississauga, Ontario$12 CAD0.5 kg
Voyageur Soap & Candle CompanySurrey, British Columbia$14 CAD0.25 kg
Windy Point Soap Making SuppliesCalgary, Alberta$13 CAD0.25 kg

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Regulatory disclaimer

FormulaNorth helps organize cosmetic formulation, label, costing, and CNF preparation information. It is not legal or regulatory advice and does not replace Health Canada guidance, professional regulatory review, or the maker's responsibility to verify product compliance before sale.